This is a schematic description of processes responsible for light emitting diode (LED) operation. The thick black lines show the energy band diagram of the conventional (a) and proposed (b) LEDs based on GaN/AlN QWs. In the conventional GaN/AlN QW LEDs the polarization field in the GaN layer enhances strongly the rate of the nonradiative Auger processes leading to reduction of the photoluminescence quantum yield and, consequently, to the "droop" effect with increase of the electrical current. In the proposed LEDs (b) the electric field acting on holes in the QW is compensated by a gradual composition variation of the variable-gap GaAlN alloy resulting in a flat valence band potential. The Auger processes in these QWs are completely suppressed and no droop effect is expected to be seen in such LEDs. (Credit: U.S. Naval Research Laboratory)

This is a schematic description of processes responsible for light emitting diode (LED) operation. The thick black lines show the energy band diagram of the conventional (a) and proposed (b) LEDs based on GaN/AlN QWs. In the conventional GaN/AlN QW LEDs the polarization field in the GaN layer enhances strongly the rate of the nonradiative Auger processes leading to reduction of the photoluminescence quantum yield and, consequently, to the "droop" effect with increase of the electrical current. In the proposed LEDs (b) the electric field acting on holes in the QW is compensated by a gradual composition variation of the variable-gap GaAlN alloy resulting in a flat valence band potential. The Auger processes in these QWs are completely suppressed and no droop effect is expected to be seen in such LEDs. (Credit: U.S. Naval Research Laboratory)
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